The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Peroxy radicals / Hydroxy-,methoxyalkylperoxy / CH2(OH)CH2O2 / JenkinCox(1991)_298K_205-300nm

DATAFILE: CH2(OH)CH2O2_JenkinCox(1991)_298K_205-300nm.txt
NAME: 2-hydroxyethylperoxy radical
FORMULA: CH2(OH)CH2O2
AUTHOR(YEAR): JenkinCox(1991)
T: 298K
λ: 205-300nm
BIBLIOGRAPHY: M.E. Jenkin and R.A. Cox, "Kinetics of reactions of CH3O2 and HOCH2CH2O2 radicals produced by the photolysis of iodomethane and 2-iodoethanol", J. Phys. Chem. 95, 3229-3237 (1991); DOI: 10.1021/j100161a049
COMMENTS: Molecular modulation technique coupled with UV absorption spectroscopy; 2-hydroxyethylperoxy radicals generated by the 254-nm photolysis of HOCH2CH2I in the presence of O2

Originally listed in the paper: relative values σ(λ)/σ(230nm) and the measured value σ(230nm) = 2.35×10-18 cm2 molecule-1

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